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Synlett 1997; 1997(12): 1467-1468
DOI: 10.1055/s-1997-1044
DOI: 10.1055/s-1997-1044
letter
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Approach to Carbocyclic 4-Deoxypyrazofurin through Asymmetrisation of a meso-Norbornene Derivative
Further Information
Publication History
Publication Date:
31 December 2000 (online)
The first enantioselective synthesis of carbocyclic 4-deoxypyrazofurin 1a has been accomplished via (+)-4 which was prepared by asymmetric hydroboration or hydrosilylation reactions.
asymmetric hydrosilylation - asymmetric hydroboration - norbornanes - carbocyclic 4-deoxypyrazofurin