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Synlett 1997; 1997(12): 1393-1394
DOI: 10.1055/s-1997-1069
DOI: 10.1055/s-1997-1069
letter
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Stereo- and Regioselective Bromination of 1,5-Cyclooctadiene Derivatives and Their Substitution Reactions with Organocopper Reagents
Further Information
Publication History
Publication Date:
31 December 2000 (online)
Bromination of tetramethyl cyclooctadiene-1,2,5,6-tetracarboxylate with N-bromosuccinimide took place with high selectivity to give the corresponding 3,7-cis-dibromide, which allowed us to introduce two (the same or different) alkyl substituents at C(3) and C(7) with one-step or stepwise use of organocopper reagents.
eight-membered carbocycle - stereoselective bromination - organocopper reagent