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Synthesis 1997; 1997(9): 1007-1009
DOI: 10.1055/s-1997-1309
DOI: 10.1055/s-1997-1309
short paper
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A Modified Procedure for the Synthesis of C3-Symmetric 'Mixed-Tail' Triphenylenes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synthesis/199709/lookinside/thumbnails/10.1055-s-1997-1309-1.jpg)
A modified procedure of the selective cleavage of three of the pentyloxy groups from 2,3,6,7,10,11-hexapentyloxytriphenylene (1) to give C3-symmetric 2,6,10-trihydroxy-3,7,11-tripentyloxytriphenylene (2) is described. The methodology has been extended to provide a convenient route to the C3-symmetric triphenylene derivative 8, with orthogonally protected carboxylic acid groups.
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