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Synthesis 1997; 1997(10): 1179-1184
DOI: 10.1055/s-1997-1321
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Synthesis of New Functionalized π-Electron Donors: Primary Hydroxy and Primary Amino Multisulfur Tetrathiafulvalenes

Laurent Binet, Jean-Marc Fabre*
  • *Laboratoire d’Hétérochimie et des Matériaux Organiques, ESA 5076, Université Montpellier II, Place Eugène bataillon, F-34095 Montpellier Cedex, France, Fax +33(4)67143888
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Publication Date:
31 December 2000 (online)

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The synthesis of new primary hydroxy- and aminotetrathiafulvalenes is described. The hydroxy derivatives 3a and 3b were synthesized from protected TTF thiolates while the amino derivatives 14a, 14b and 17 were prepared from the corresponding hydroxyTTFs using Gabriel synthesis or azide reduction. The synthesis of new amphiphilic bis(hydroxy)- and bis(amino)TTFs is also reported.

mono- and difunctionalized tetrathiafulvalenes - primary alcohols - primary amines - amphiphilic derivatives