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Synthesis 1997; 1997(12): 1391-1393
DOI: 10.1055/s-1997-1364
short paper
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Synthesis of 1,2,3,6-Tetrahydrophosphorin 1-Oxides by Regioselective Reduction

Györg Keglevich1 , Zsolt Böcskei2 , Kálmán Újszászy3 , László Tőke4
  • 1Department of Organic Chemical Technology, Technical University of Budapest, 1521 Budapest, Hungary, Fax +36(1)4633648; E-mail: keglevich@oct.bme.hu
  • 2Chinoin Pharmaceuticals, 1325 Budapest, Hungary
  • 3Department of General and Inorganic Chemistry, Loránd Eötvös University, 1518 Budapest, Hungary
  • 4Department of Organic Chemical Technology, Technical University of Budapest, 1521 Budapest, Hungary
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Publikationsdatum:
31. Dezember 2000 (online)

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The title compounds 2a-e have been synthesized by the partial saturation of the hetero ring of 1,2-dihydrophosphorin 1-oxides 1a-e. The reduction was accomplished through regioselective hydroboration.

1,2-dihydrophosphorin - regioselective reduction - hydroboration - 1,2,3,6-tetrahydrophosphorin - stereostructure