Download PDF
Synthesis 1997; 1997(6): 668-672
DOI: 10.1055/s-1997-1391
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

New Applications of Dimethyl Pentacyclo[6.4.0.02,10.03,7.04,9]dodeca-5,11-diene-8,9-dicarboxylate in the Synthesis of Polycyclic Compounds

Pelayo Camps* , Oscar Coll, Francesc Pérez, Santiago Vázquez
  • *Laboratori de Química Farmacéutica, Facultat de Farmàcia, Universitat de Barcelona, Av. Diagonal s/n; E-08028 Barcelona, Spain, Fax +34(3)4021886; E-mail: camps@farmacia.far.ub.es
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

A short synthesis of diester 9 and the first synthesis of dimethyl 8,9-dihydrotriquinacene-2,6-dicarboxylate (10 from the readily available pentacyclic diester 1 is described.

dimethyl tetracyclo[5.2.1.02,6.03,8]decane-7,8-dicarboxylate - dimethyl 8,9-dihydrotriquinacene-2,6-dicarboxylate - iodosobenzene diacetate - 2,2'-dithiopyridine 1,1'-dioxide - oxidative decarboxylation/fragmentation