Synthesis and Reactions of Chiral α-Lithiophosphoric Triamides

Jürgen F. K. Müller; Bernhard Spingler; Margareta Zehnder

doi:10.1055/s-1997-1526

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Synlett 1997; 1997(9): 1059-1060
DOI: 10.1055/s-1997-1526

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Synthesis and Reactions of Chiral α-Lithiophosphoric Triamides

Jürgen F.K. Müller¹ , Bernhard Spingler, Margareta Zehnder²

¹Institute for Inorganic Chemistry, Laboratory for Crystallography, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland, Fax +41 61 267 1018; E-mail muellerju@ubaclu.unibas.ch
²Institute for Inorganic Chemistry, Laboratory for Crystallography, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland, Fax +41 61 267 1018

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Publikationsdatum:
31. Dezember 2000 (online)

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The synthesis of a novel chiral phosphoric triamide 2 is reported. Lithiated 2 undergoes regio- and diastereoselective addition reactions with various electrophiles.

phosphoric triamides - α-aminobenzyl anions - chiral lithio compounds - diastereoselective alkylations