PDF herunterladen
Synlett 1997; 1997(6): 687-688
DOI: 10.1055/s-1997-3244
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Enantioselective Olefin Epoxidation with Chiral Manganese/1,4,7-Triazacyclononane Complexes

Carsten Bolm* , Dieter Kadereit, Michaela Valacchi
  • *Institut für Organische Chemie der RWTH Aachen, Professor Pirlet-Str. 1, D-52056 Aachen, Germany, Fax (Int.) 241 8888 391; e-mail Carsten.Bolm@RWTH-Aachen.de
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 2000 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Complexes prepared in situ from chiral N-substituted 1,4,7-triazacyclononanes and manganese(II) acetate catalyze the asymmetric oxidation of unfunctionalized olefins with hydrogen peroxide to give optically active epoxides under mild reaction conditions.

triazacyclononane - manganese complexes - hydrogen peroxide - catalysis - epoxidation