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Synlett 1997; 1997(6): 687-688
DOI: 10.1055/s-1997-3244
DOI: 10.1055/s-1997-3244
letter
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Enantioselective Olefin Epoxidation with Chiral Manganese/1,4,7-Triazacyclononane Complexes
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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Complexes prepared in situ from chiral N-substituted 1,4,7-triazacyclononanes and manganese(II) acetate catalyze the asymmetric oxidation of unfunctionalized olefins with hydrogen peroxide to give optically active epoxides under mild reaction conditions.
triazacyclononane - manganese complexes - hydrogen peroxide - catalysis - epoxidation