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Synlett 1997; 1997(6): 661-662
DOI: 10.1055/s-1997-3245
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Polar Additives as Cocatalyst in Glycosidation

Jadwiga Bogusiak1 , Wieslaw Szeja2
  • 1Faculty of Pharmacy, Silesian Medical School, Pl-41-200 Sosnowiec, Poland, FAX: 048 (032) 192 54 05
  • 2Department of Chemistry, Silesian Technical University, Pl-44-100 Gliwice, Poland
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Publikationsdatum:
31. Dezember 2000 (online)

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Selective 1,2-cis glycofuranoside synthesis with dithiocarbonates and dithiocarbamates was effected under mild conditions by combined use of silver triflate and a catalytic amount of polar organic compounds i.e. DMSO, tetramethylurea, HMPA.

glycosidation - glycofuranosyl donors - dithiocarbamates - dithio carbonates - glycofuranosides