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Synlett 1997; 1997(7): 799-800
DOI: 10.1055/s-1997-5752
DOI: 10.1055/s-1997-5752
letter
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Asymmetric Synthesis of Unsaturated Pipecolic Acid Derivatives
Further Information
Publication History
Publication Date:
31 December 2000 (online)
Two enantiopure pipecolic acid derivatives having an olefinic moiety were synthesized from an intramolecular addition of allyl silanes on an iminium double bond. The iminium moiety was generated via a reaction of chiral β-amino alcohols with glyoxal.
allyl silanes - iminium ions - unsaturated α-amino acids