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Synlett 1997; 1997(7): 786-788
DOI: 10.1055/s-1997-5775
DOI: 10.1055/s-1997-5775
letter
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α-Acetyl- and α-Cyanovinyl 2,4-Dinitrophenyl Carboxylate as Useful Ketene Equivalents for the Diels-Alder Reaction
Further Information
Publication History
Publication Date:
31 December 2000 (online)
Two ketene equivalents (5 and 35) have been developed for use in the Diels-Alder reaction. These dienophiles exhibit a marked increase in reactivity in comparison with the more conventional acetoxyacrylonitrile. Conversions of the cycloadducts to the requisite ketones occurs under mild, and moderate to high yielding conditions.
Diels-Alder - reactive ketene equivalents