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Synlett 1997; 1997(3): 287-288
DOI: 10.1055/s-1997-757
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Kinetic Resolution of Eucarvone Tricarbonyliron Complex with Sparteine-N-oxides

Tanja Petrowitsch, Peter Eilbracht*
  • *Organische Chemie I (Fb 3), Universität Dortmund, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany, Fax: (+49) (0)231/7555364; e-mail: eilbrach@citrin.chemie.uni-dortmund.de
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Publication History

Publication Date:
31 December 2000 (online)

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The kinetic resolution of the racemic eucarvone complex 1 using chiral amine oxides 3a-c as oxidizing agents leads to optically enriched complexes 1 and 2 with up to 64% ee. The absolute configuration of the chiral complexes 1 and 2 is determined by their CD spectra.

kinetic resolution - tricarbonyliron complex - chiral N-oxides - CH spectra - absolute configuration