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Synlett 1997; 1997(10): 1199-1201
DOI: 10.1055/s-1997-998
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Pd(II)-Catalyzed Oxidative Homo-Coupling of Aryl-Metal Compounds Using Acrylate Dibromide Derivatives as Effective Oxidants

Shigehiro Yamaguchi, Shigeki Ohno, Kohei Tamao*
  • *Institute for Chemical Research, Kyoto University, Uji, Kyoto 611, Japan, FAX (81)-774-38-3186; e-mail tamao@scl.kyoto-u.ac.jp
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Publication History

Publication Date:
31 December 2000 (online)

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In the presence of acrylate dibromides, palladium(II)-complexes catalyze the oxidative homo-coupling of arylstannanes, areneboronic acids, and arylfluorosilanes to afford biaryls in good yields.

oxidative homo-coupling - Pd(II) catalyst - aryl-metal compound - acrylate dibromide - oxidant