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Synlett 1998; 1998(2): 166-168
DOI: 10.1055/s-1998-1591
DOI: 10.1055/s-1998-1591
letter
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Ruthenium-Catalyzed Yne-Ene Cross Metathesis Binding to Solid Support and Cleavage by Pd0-Catalysis
Further Information
Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199802/lookinside/thumbnails/10.1055-s-1998-1591-1.jpg)
The solid phase synthesis of 1,3-dienes by yne-ene cross-metathesis involving binding of terminal alkenes to polystyrene resins, which contain propargyl ester groups, and their cleavage by Pd0-catalysis under C,C- or C,N-bond formation or reduction is demonstrated.
metathesis - catalytic immobilization - 1,3-dienes - combinatorial chemistry - Pd-catalysis