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Synlett 1998; 1998(8): 865-868
DOI: 10.1055/s-1998-1808
DOI: 10.1055/s-1998-1808
letter
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Polymer Bound 3,5-Cyclohexadiene-1,2-diols as Core Structures for the Development of Small Molecule Libraries
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Publication History
Publication Date:
31 December 2000 (online)
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A highly efficient sequence for the synthesis of complex, chiral and highly functionalized molecules on solid phase is reported. Solid phase bound cyclohexadiene-diols were derivatized through epoxidation, nucleophilic ring opening, Pd(0) cross-couplings and Diels-Alder reactions.
solid phase synthesis - epoxidation - epoxide opening - Pd(0)-coupling - Diels-Alder reaction