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Synlett 1998; 1998(8): 847-848
DOI: 10.1055/s-1998-1821
DOI: 10.1055/s-1998-1821
letter
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Asymmetric Synthesis XXVIII: Novel Chiral Aminophosphine Phosphinite Ligand and Its Application in Homogenous Catalytic Asymmetric Hydrogenation of Dehydroamino Acid Derivatives
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Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199808/lookinside/thumbnails/10.1055-s-1998-1821-1.jpg)
Novel chiral aminophosphine phosphinite, DPAMPP was designed and synthesized from (1S,2R)-1,2-diphenyl-2-aminomethanol. Its cationic rhodium complex has been found to be an excellent catalyst for enantioselective hydrogenation of dehydroamino acids (more than 95.0% e.e.).
chiral aminophosphine phosphinite ligand - catalytic asymmetric hydrogenation - optically active amino acid derivatives