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Synlett 1998; 1998(12): 1317-1318
DOI: 10.1055/s-1998-1981
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Synthesis of β,β-Bis(trimethylstannyl)styrenes by Organometal Trapping of Intermediates in the Aromatic Vinylation Reactions

Masahiko Yamaguchi* , Katsumi Kobayashi, Mieko Arisawa
  • *Faculty of Pharmaceutical Sciences, Tohoku University, Aoba, Sendai 980-8578, Japan; Fax 81-22-217-6811; E-mail: yama@mail.pharm.tohoku.ac.jp
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Publication History

Publication Date:
31 December 2000 (online)

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β,β-Bis(trimethylstannyl)styrenes were synthesized by organo-metal trapping of β,β-bis(trichlorostannyl)styrenes, which were formed by the reaction of ethyne with phenols or anilines in the presence of SnCl4-Bu3N reagent.

β,β-bis(trimethylstannyl)styrenes - SnCl4-Bu3N reagent - phenol - aniline - ethyne