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Synlett 1998; 1998(12): 1347-1348
DOI: 10.1055/s-1998-1990
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Lanthanide Perfluoroalkylsulfonylamide Catalysts for Fluorous Phase Organic Synthesis

Joji Nishikido* , Hitoshi Nakajima, Takao Saeki, Akihiro Ishii, Koichi Mikami
  • *Noguchi Research Institute, Itabashi-ku, Tokyo 173-0003, Japan; Fax 3 5734 2776; E-mail: kmikami@o.cc.titech.ac.jp
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Publication History

Publication Date:
31 December 2000 (online)

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Lanthanide perfluoroalkylsulfonylamide complexes catalyze the Friedel-Crafts acylation and Diels-Alder reaction more efficiently than AlCl3 and Yb(OTf)3 in benzotrifluoride and hexafluoro-p-xylene.

lanthanide perfluoroalkylsulfonylamide complexes - benzotrifluoride - hexafluoro-p-xylene - Friedel-Crafts acylation - Diels-Alder reaction