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Synlett 1998; 1998(6): 588-589
DOI: 10.1055/s-1998-3134
DOI: 10.1055/s-1998-3134
letter
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A 1,3-Dipolar Cycloaddition Route to 7-Azanorbornanes: Application to the Synthesis of syn-Facial N-Bridged Polynorbornanes
Further Information
Publication History
Publication Date:
31 December 2000 (online)
Aziridinocyclobutenes react with electron-deficient or ring-strained alkenes to produce 7-azanorbornenes in a novel 1,3-dipolar cycloaddition reaction suitable for block assembly protocols. Benzo-7-azanorbornadiene and 7-heterobridged analogues react stereoselectively to produce compounds with syn-facial orientation of their bridges.
1,3-dipolar cycloaddition - stereospecific - invertomers - 7-azanorbornenes - aziridines