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Synlett 1999; 1999(4): 438-440
DOI: 10.1055/s-1999-2638
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Novel and Unexpected Deamination during the Palladium-Catalysed Cross-Coupling of Haloanilines and Arylboronic Acids

Michael Hird* , Alexander J. Seed, Kenneth J. Toyne
  • *The Department of Chemistry, The University of Hull, Hull, HU6 7RX, UK; Fax +44(14 82)46 64 10; E-mail: M.Hird@chem.hull.ac.uk
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Publication Date:
31 December 1999 (online)

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Palladium-catalysed cross-coupling reactions involving haloanilines and arylboronic acids produce the expected biaryl products, but additionally a substantial quantity of the corresponding deaminated biaryl is also generated which constitutes a novel synthetic methodology.

deamination - palladium-catalysed - cross-coupling - arylboronic acids