Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml
Synlett 1999; 1999(6): 816-818
DOI: 10.1055/s-1999-2729
DOI: 10.1055/s-1999-2729
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Oxovanadium(IV) Complex-mediated Catalysis in Mukaiyama-type Aldol Additions
Further Information
Publication History
Publication Date:
31 December 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199906/lookinside/thumbnails/10.1055-s-1999-2729-1.jpg)
Condensation of vanadyl sulfate with 2,2′-biphenol in the presence of N-containing ligands provides oxovanadium(IV) complexes which serve as efficient catalysts in Mukaiyama aldol reactions to afford aldol products in 52-100% yields with diastereoselectivities of up to 90/10 (anti/syn).
Lewis acids - 2,2′-biphenol - N-methylimidazole - diastereoselective - β-hydroxyesters