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Synlett 1999; 1999(7): 1057-1058
DOI: 10.1055/s-1999-2748
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Copper (I) Mediated Conjugate Addition of Grignard Reagents to 2-Oxoethylcyclohexenols. A Versatile, Efficient and Diastereoselective Route to anti, Z 6-Alkyl-2-trialkylsilyloxy-1-(2-trimethylsilyloxypropylid-1-ene)-cyclohexanes

Valéry Dambrin* , Monique Villiéras, Hassen Amri, Jacques Lebreton, Jean Villiéras
  • *Laboratoire de Synthèse Organique, UMR CNRS 6513, Faculté des Sciences et Techniques, 2, rue de la Houssinière, BP 92208 - F44322 Nantes Cedex 03, France; Fax +33(2)51 12 54 12; E-mail: villiera@chimie.univ-nantes.fr
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Publication Date:
31 December 1999 (online)

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conjugate addition - polyfunctional Michael acceptor - enolate trapping - silyl enols ethers - diastereoselectivity