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Synlett 1999; 1999(9): 1407-1408
DOI: 10.1055/s-1999-2847
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Studies on the Synthesis of the Zaragozic Acids: Discovery of a Novel Cascade Sequence

Philip J. Parsons* , Tamsyn Montagnon, Mel Giles, Peter Hitchcock
  • *The Chemical Laboratories, CPES, Sussex University, Falmer, Brighton, East Sussex, BN1 9QT, UK; E-mail: p.j.parsons@sussex.ac.uk
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Publication Date:
31 December 1999 (online)

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Studies towards the synthesis of the zaragozic acids are reported. A novel rearrangement has been uncovered which gives the unexpected dimer (10).

zaragozic acid - squalestatin - sigmatropic shift - epoxidation - 7-oxabicyclo[2,2,1]heptane