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Synlett 1999; 1999(9): 1415-1416
DOI: 10.1055/s-1999-2874
DOI: 10.1055/s-1999-2874
letter
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Reduction of Organic Halides with Tri-2-Furanylgermane: Stoichiometric and Catalytic Reaction
Further Information
Publication History
Publication Date:
31 December 1999 (online)
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Triethylborane-induced radical reduction of organic halides with tri-2-furanylgermane provided the corrresponding reduced compounds in good yields. Radical cyclization of β-haloalkyl allyl ether or 6-halo-1-alkene afforded five-membered products under the same reaction conditions. These reactions proceeded with NaBH4 in the presence of a catalytic amount of germanium hydride.
tri-2-furanylgermane - triethylborane - reduction - radical reaction