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Synlett 1999; 1999(10): 1567-1568
DOI: 10.1055/s-1999-2917
DOI: 10.1055/s-1999-2917
letter
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Highly Regioselective Silaboration of 3-Substituted 1,2-Dienes Catalyzed by Palladium/2,6-Xylyl Isocyanide
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Publication History
Publication Date:
31 December 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199910/lookinside/thumbnails/10.1055-s-1999-2917-1.jpg)
Regioselective silaboration of 3-substituted 1,2-dienes was efficiently catalyzed by palladium/2,6-xylyl isocyanide complex, affording an adduct, in which the boryl and silyl groups were introduced at the central allenyl carbon and at the substituted allenyl carbon, respectively.
silaboration - allenes - palladium/2,6-xylyl isocyanide - regioselectivity - 2-boryl allylsilane