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Synlett 1999; 1999(4): 435-437
DOI: 10.1055/s-1999-3157
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C-Furanoside Synthesis via Intramolecular Cyclization

David Egron* , Thierry Durand, Arlene Roland, Jean-Pierre Vidal, Jean-Claude Rossi
  • *Laboratoire de Chimie Biomoléculaire et Interactions Biologiques associé au C.N.R.S., Université Montpellier I, Faculté de Pharmacie, 15 Av. Ch. Flahault, F-34060 Montpellier, France; Fax +33(4)67 54 86 25; E-mail: Thierry.Durand@pharma.univ-montp1.fr
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Publication Date:
31 December 1999 (online)

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Polysubstituted C-furanoside 8, with the correct absolute configuration is readily available from diacetone-d-glucose. This C-furanoside after deprotection should be a useful synthon for natural product synthesis.

C-furanoside - intramolecular cyclization - absolute configuration steady-state NOE - diacetone-d-glucose