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Synthesis 1999; 1999(5): 754-756
DOI: 10.1055/s-1999-3486
DOI: 10.1055/s-1999-3486
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Efficient and Regioselective Access to Bis-heterocycles via Palladium-Catalysed Coupling of Organostannanes and Organozincates Derived from C-6 Lithiated 2-Methoxypyridine
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Publication History
Publication Date:
31 December 1999 (online)
![](https://www.thieme-connect.de/media/synthesis/199905/lookinside/thumbnails/10.1055-s-1999-3486-1.jpg)
The efficient and regioselective synthesis of various bisheterocyclic compounds was performed using a regioselective onepot lithiation-transmetallation-cross-coupling of α-methoxypyridine.
C-6 lithiation - cross-coupling of heterocycles - 2-methoxy-6-(tributylstannyl)pyridine - 6-bromozinc-2-methoxypyridine