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Synthesis 1999; 1999(5): 754-756
DOI: 10.1055/s-1999-3486
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Efficient and Regioselective Access to Bis-heterocycles via Palladium-Catalysed Coupling of Organostannanes and Organozincates Derived from C-6 Lithiated 2-Methoxypyridine

Philippe Gros* , Yves Fort
  • *Synthèse Organique et Réactivité, UMR 7565, Université de Nancy-1, Faculté des Sciences, BP239, F-54506 Vandoeuvre-Les-Nancy, France; Fax +33(3)83 40 45 58; E-mail: Yves.Fort@sor.u-nancy.fr
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Publikationsdatum:
31. Dezember 1999 (online)

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The efficient and regioselective synthesis of various bisheterocyclic compounds was performed using a regioselective onepot lithiation-transmetallation-cross-coupling of α-methoxypyridine.

C-6 lithiation - cross-coupling of heterocycles - 2-methoxy-6-(tributylstannyl)pyridine - 6-bromozinc-2-methoxypyridine