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Synthesis 1999; 1999(1): 107-111
DOI: 10.1055/s-1999-3666
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Stereospecific Synthesis of (E,Z)- and (Z,Z)-Hexadeca-10,12-dienal. Sex Pheromone Components of Diaphania hyalinata

Jorge A. Cabezas* , Allan C. Oehlschlager
  • *Department of Chemistry, Simon Fraser University, Burnaby, British Columbia, V5A 1S6, Canada; Fax JAC: +1(5 06)2 53-50 20; ACO: +1(5 06)2 61-53 97; E-mail: JAC: jcabezas@cariari.ucr.ac.cr; ACO: chemtica@sol.racsa.co.cr
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Publication Date:
31 December 1999 (online)

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Isomeric (E,Z)- and (Z,Z)-hexadeca-10,12-dienal were prepared, stereospecifically, in 51% and 43% overall yields from dec-1-yne.

(E,Z)-hexadeca-10,12-dienal - (Z,Z)-hexadeca-10,12-dienal - dec-1-yne - stereospecific reaction