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Synthesis 2000; 2000(7): 917-920
DOI: 10.1055/s-2000-6288
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Synthesis and Reactivity of Functionalized Alkynyl Titanium Derivatives

Natalia Morlender-Vais* , Julia Kaftanov, Ilan Marek
  • *Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Technion City, Haifa 32000 Israel; Fax (972)48233735; E-mail: chilanm@tx.technion.ac.il
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Publikationsdatum:
31. Dezember 2000 (online)

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The in situ formation of Ti(II) and subsequent reaction with halogeno alkynes offer a new route to the preparation of functionalized alkynyl titanium derivatives, which can then react chemoselectively with functionalized electrophiles.

titanium - functionalized organometallic - halogeno alkynes - alkynes