Download PDF
Synthesis 2000; 2000(5): 738-742
DOI: 10.1055/s-2000-6386
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis and Properties of β-Ethoxyvinyl Polyfluoroalkyl Ketones

Marine G. Gorbunova* , Igor I. Gerus, Valery P. Kukhar
  • *Institute of Bioorganic Chemistry, National Academy of Sciences, Murmanskaya I, Kiev-94, 253660, Ukraine; Fax + 38(0 44)5 73 25 52; E-mail: igerus@alfacom.net
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

A number of β-ethoxyvinyl polyfluoroalkyl ketones were synthesized by acylation of ethyl vinyl ether with acid chlorides containing polyfluoroalkyl groups of different composition and structure. Some typical nucleophilic reactions of the title compounds with amines were carried out. Two new fluoro-containing pyrimidinoles were synthesized by the reaction of β-ethoxyvinyl polyfluoroalkyl ketones with urea.

acylations - fluorinated building blocks - enones - enaminones - aminations