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Synlett 2000; 2000(1): 140-1042
DOI: 10.1055/s-2000-6474
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[tBu2SnOH(Cl)]2 as a Highly Efficient Catalyst for Deacetylation

Akihiro Orita* , Katsumasa Sakamoto, Yuuki Hamada, Junzo Otera
  • *Department of Applied Chemistry, Okayama University of Science, Ridai-cho, Okayama 700-0005, Japan
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Publication Date:
31 December 2000 (online)

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The title compound effects deacetylation of acetates under almost neutral conditions. A variety of functional groups are tolerated and high selectivities are attained in competitions between primary, secondary, and tertiary alcohol acetates.

organotin compound - Lewis acid - deacetylation - acetate