Download PDF
Synlett 2000; 2000(9): 1351-1353
DOI: 10.1055/s-2000-7144
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

One-Pot Conversion of Oximes to N-(tert-Butoxycarbonyl) Amines with Polymethylhydrosiloxane, Pd-C and Di-tert-butyl Dicarbonate

S. Chandrasekhar* , M. Venkat Reddy, L. Chandraiah
  • *Indian Institute of Chemical Technology, Hyderabad 500 007, India; Fax +91 40 7 17 33 87; E-mail: srivaric@iict.ap.nic.in
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

N-(tert-butoxycarbonyl) amines are directly obtained from oximes of aldehydes and ketones in one-pot when treated with polymethylhydrosiloxane (PMHS) and di-tert-butyl dicarbonate in the presence of catalytic amount of 10% Pd-C for the first time.

polymethylhydrosiloxane - oximes - tert-butylcarbamates - one-pot reaction