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Synthesis 2000; 2000(11): 1539-1542
DOI: 10.1055/s-2000-7597
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A Mild One-Pot Procedure for the Polynitration of Activated Arenes. Convenient Preparation of Dinitro- and Trinitrodialkoxybenzenes

Masatoshi Nose* , Hitomi Suzuki
  • *Department of Chemistry, School of Science, Kwansei Gakuin University, Uegahara 1-1-155, Nishinomiya 662-8501, Japan; Fax + 81 (7 98) 51 09 14; E-mail: hsuzuki@kwansei.ac.jp
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Publication Date:
31 December 2000 (online)

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When first treated with an excess of nitrogen dioxide alone and then in the presence of ozone at low temperature, dialkoxybenzenes are smoothly and stepwise polynitrated in a one-pot manner to afford the corresponding dinitro or trinitro derivatives in good yield.

dialkoxybenzenes - nitration - polynitro compounds - nitrogen dioxide - ozone