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Synthesis 2000; 2000(11): 1547-1556
DOI: 10.1055/s-2000-7601
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New Phenyl 6,4′-Substituted-1-Thio-β-Maltosides, Building Blocks for The Synthesis of Linear and Branched Malto-oligosaccharides

Mohammed Saddik Motawia* , Kim Larsen, Carl Erik Olsen, Birger Lindberg Møller
  • *Plant Biochemistry Laboratory, Department of Plant Biology, The Royal Veterinary and Agricultural University, 40 Thorvaldsensvej, DK-1871 Frederiksberg C, Copenhagen, Denmark
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Publication Date:
31 December 2000 (online)

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An efficient strategy to synthesize a number of new phenylthio-maltoside derivatives in yields from 55 to 95% is described. These derivatives can be used as suitable building blocks for stepwise synthesis of starch derived malto-oligosaccharides.

phenyl 1-thio-β-maltoside - benzylidenation - silylation - benzylation - regioselective reductive cleavage