Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 2000; 2000(11): 1598-1602
DOI: 10.1055/s-2000-7603
DOI: 10.1055/s-2000-7603
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
An Efficient and Practical Tin Free Procedure for Radical Iodine Atom-Transfer Reactions
Further Information
Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synthesis/200011/lookinside/thumbnails/10.1055-s-2000-7603-1.jpg)
Iodine atom-transfer is a non-reductive and very attractive way of performing radical reactions that is usually achieved in the presence of hexaalkyldistannanes. We report here an efficient procedure to run such reactions in the absence of ditin derivatives. The iodine atom transfers are performed via thermal initiation with commercially available and cheap dilauroyl peroxide (DLP). Good yields for intra- and intermolecular addition to alkenes are obtained. One example of aromatic substitution for the synthesis of an indolone derivative using stoichiometric amount of DLP is also reported.
radical reactions - iodine - peroxides - isomerization - ring closure