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Synthesis 2000; 2000(11): 1561-1564
DOI: 10.1055/s-2000-7605
DOI: 10.1055/s-2000-7605
paper
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Copper(I)-Catalyzed Intramolecular Addition of N-Chloroamines to Double Bonds under Aprotic Conditions. Towards a Stereoselective Catalytic Radical Reaction
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Publication History
Publication Date:
31 December 2000 (online)
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Copper(I) complexes catalyze the intramolecular addition of N-chloramines to carbon-carbon double bonds under neutral conditions, a reaction that proceeds via a metal complexed aminyl radical. A high diastereoselectivity is obtained in the cyclization step due to the sterically demanding copper complex.
catalysis - copper - diastereoselectivity - piperidines - radical reactions