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Synlett 2000; 2000(10): 1443-1446
DOI: 10.1055/s-2000-7621
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Synthesis of 1-Aryl-2-vinylcycloalkanes by Intramolecular Carbolithiation

Alain Krief* , Bruno Remacle, Joel Mercier
  • *Laboratoire de Chimie Organique de Synthèse, Department of Chemistry, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, B-5000 Namur, Belgium; Fax + 32 (0 81) 46 12 41; E-mail: alain.krief@fundp.ac.be
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Publication Date:
31 December 2000 (online)

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Benzyl selenides bearing a side chain possessing in suitable position an allylic ether react with butyllithiums and produce, via the corresponding benzyllithiums, 1-aryl-2-vinylcyclopentanes.

lithiation - alkanes