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Synlett 2000; 2000(11): 1589-1592
DOI: 10.1055/s-2000-7919
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A New Efficient Palladium Catalyst for Heck Reactions of Deactivated Aryl Chlorides

Andreas Ehrentraut* , Alexander Zapf, Matthias Beller
  • *Institut für Organische Katalyseforschung an der Universität Rostock e. V., Buchbinderstraße 5-6, D-18055 Rostock, Germany; Fax +49-38 14 66 93 24; E-mail: matthias.beller@ifok.uni-rostock.de
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Publication Date:
31 December 2000 (online)

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A new palladium catalyst consisting of Pd(Dba)2 and di-1-adamantyl-n-butylphosphine is described for the Heck reaction of non-activated and deactivated aryl chlorides. The new catalyst is more efficient and gives improved results compared to the previously known best catalyst system.

homogeneous catalysis - Heck reaction - palladium - aryl chlorides