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Synthesis 2000; 2000(12): 1756-1760
DOI: 10.1055/s-2000-8206
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Dioxolane-Derived Carbanions and Their Reactivity

Silvia Carini* , Vanda Cerè, Francesca Peri, Salvatore Pollicino
  • *Department of Organic Chemistry, "A. Mangini" - University of Bologna, Viale Risorgimento, 4, I-40136 Bologna, Italy; Fax +39 (51) 2 09 36 54; E-mail: pollicin@ms.fci.unibo.it
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Publication Date:
31 December 2000 (online)

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The generation of negatively charged species by treatment of dioxolanes with BuLi or via fluorodesilylation, results in the formation of new compounds, by spontaneous cycloelimination or upon quenching with C-electrophiles.

carbanions - β-eliminations - silyl dioxolanes - organometallic reagents - lithium