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Synthesis 2000; 2000(12): 1659-1661
DOI: 10.1055/s-2000-8209
short paper
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Bis(dealkoxycarbonylation) of Nitroarylmalonates: A Facile Entry to Alkylated Nitroaromatics

Mukund Gurjar* , Dandepally Srinivasa Reddy, Andappan Murugaiah, Subbaiah Murugaiah
  • *National Chemical Laboratory, Pune-411 008, India; E-mail: gurjar@dalton.ncl.res.in
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Publication Date:
31 December 2000 (online)

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A simple approach to alkylated nitroaromatics from substituted nitroaryl malonic esters by double decarboxylation is detailed.

nucleophilic aromatic substitutions - Krapcho's decarboxylation - alkylations - nitrotoluene - arenes