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Synthesis 2001; 2001(2): 0312-0316
DOI: 10.1055/s-2001-10800
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Synthesis of Building Blocks for Carba-oligosaccharides: 5a′-Carbamaltose and 5a′-Carbacellobiose, and 5a-Carba-β-d-mannopyranosyl-(1→4)-d-glucopyranose

Seiichiro Ogawa* , Masahiro Ohmura, Seiichi Hisamatsu
  • *Department of Applied Chemistry, Faculty of Science and Engineering, Keio University, Hiyoshi, Kohoku-ku, Yokohama, 223-8522 Japan; Fax +81(45)5661551; E-mail: ogawa§applc.keio.ac.jp
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Publication Date:
31 December 2001 (online)

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Practical synthesis of ether-linked 5a′-carbamaltose and -cellobiose, and the related carbadisaccharide starting from a sole condensate of the 1,2-anhydro-3-O-benzyl-4,6-O-benzylidene-5a-carba-β-d-mannopyranose and methyl 2,3,6-tri-O-benzyl-α-d-glucopyranoside is described.

cyclitols - carbohydrate mimics - pseudo-oligosaccharides - carba-oligosaccharides - ether-linked 5a-carbadisaccharides