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Synthesis 2001; 2001(3): 0349-0357
DOI: 10.1055/s-2001-11421
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α-Phosphonovinyl Carbanions in Organic Synthesis

Toru Minami* , Tatsuo Okauchi, Ryoji Kouno
  • *Department of Applied Chemistry, Kyushu Institute of Technology, Sensui-cho, Tobata, Kitakyushu 804-8550, Japan; Fax + 81(93)8 84 33 00; E-mail: minami@che.kyutech.ac.jp
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Publication Date:
31 December 2001 (online)

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The generation of several α-phosphono-substituted vinyl carbanions is described. The α-phosphonovinyl carbanions have been used to afford versatile vinylphosphonate reagents capable of a wide range of synthetic transformations.

phosphonates - phosphorus - vinyl carbanions - metalation - lithiation - Horner-Wadsworth-Emmons reaction