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Synlett 2001; 2001(4): 0550-0552
DOI: 10.1055/s-2001-12316
DOI: 10.1055/s-2001-12316
letter
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Aryltrifluoromethylsulfoxides: Sulfinylation or Aromatics by Triflinate Salts in Acid Medium
Further Information
Publication History
Publication Date:
31 December 2001 (online)
Direct sulfinylation reaction of simple aromatic compounds by triflinate salts in triflic acid led to aryltrifluoromethyl sulfoxides. The para isomer was the major one. The regioselectivity of the reaction was very high when the substituent on the aromatic ring was a halogen atom, a trifluoromethoxy group or an acetanilide function.
aryltrifluoromethylsulfoxides - sulfinylation - electrophilic reactions