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Synthesis 2001(6): 0841-0844
DOI: 10.1055/s-2001-13401
DOI: 10.1055/s-2001-13401
PAPER
© Georg Thieme Verlag Stuttgart · New York
A Convenient and General Synthesis of Cata- and Peri-Condensed Polycyclic Aromatic Hydrocarbons with a Fjord-Region
Weitere Informationen
Received
19 November 2000
Publikationsdatum:
24. September 2004 (online)
Publikationsverlauf
Publikationsdatum:
24. September 2004 (online)
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Abstract
Cata- and peri-condensed polycyclic aromatic hydrocarbons (PAHs) 10a-d and 11 have been conveniently synthesized by the application of Suzuki cross-coupling reaction. In three to four steps, these PAHs having fjord-region were obtained in an overall yield of 35-51% from commercially or easily accessible aryl boronic acids and aryl bromides.
Key words
polycyclic aromatic hydrocarbons - aryl boronic acids - Suzuki cross-coupling reaction - 2-(aryl)benzaldehyde - dibenzo[c,mno]chrysene - naphtho[8,1,2-ghi]chrysene
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