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Synlett 2001; 2001(Special Issue): 0904-0906
DOI: 10.1055/s-2001-14662
DOI: 10.1055/s-2001-14662
letter
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The First Total Synthesis of Sphingofungin E and the Determination of its Stereochemistry
Further Information
Publication History
Publication Date:
31 December 2001 (online)
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The total synthesis of sphingofungin E has been realized for the first time and its absolute configurations were established. Starting from l-(+)-tartaric acid, our synthesis featured substrate-controlled asymmetric dihydroxylation, regiospecific epoxide formation and Hatakeyama reaction to construct the contiguous chiral centers in the target molecule.
total synthesis - amino acids - dihydroxylations - Wittig reactions - epoxides