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Synlett 2001; 2001(7): 1065-1078
DOI: 10.1055/s-2001-15133
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Synthesis and Properties of Phosphorus Ylides Containing Fluorine Atoms Bonded to Phosphorus

Oleg I. Kolodiazhnyi* , Reinhard Schmutzler
  • *Department of Physiologically Active Compound Synthesis, Institute of Bioorganic Chemistry, National Academy of Sciences, Murmanskaya Street 1, Kiev, Ukraine; Fax + 38(044)573-25 52; E-mail: oik@bpci.kiev.ua
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Publication Date:
31 December 2001 (online)

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Methods for preparation of phosphorus ylides substituted at the phosphorus atom of the P=C group with fluorine atoms, their properties and application in synthesis are reviewed. The bibliography includes 77 references.

P-fluoro ylides - phosphorylated ketenes - allylphosphonates - 2-fluoro-1,2λ 2-oxaphosphetanes - "abnormal" Wittig Reaction