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Synlett 2001; 2001(7): 1109-1112
DOI: 10.1055/s-2001-15146
DOI: 10.1055/s-2001-15146
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Diastereoselective, One-Pot Synthesis of γ-Amino Alcohols from Ketimines
Further Information
Publication History
Publication Date:
31 December 2001 (online)
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Deprotonation of ketimines with lithium diisopropyl amide, followed by reaction with aldehydes and subsequent reduction with aluminium hydrides gave γ-amino alcohols with moderate to good syn selectivity. The scope and limitations of this preparative method are reported.
diastereoselectivity - reduction - amino alcohols - ketimines - amide bases