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Synlett 2001; 2001(7): 1125-1126
DOI: 10.1055/s-2001-15148
DOI: 10.1055/s-2001-15148
letter
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Elaboration of New Monoterpenoid Indole Alkaloids Containing a Dihydrofuran Unit
Further Information
Publication History
Publication Date:
31 December 2001 (online)
![](https://www.thieme-connect.de/media/synlett/200107/lookinside/thumbnails/10.1055-s-2001-15148-1.jpg)
Reaction of methyl fluorodiethylphosphonoacetate with N4-Boc-3-formylmethyl-tetrahydro-β-carboline gave the corresponding methyl fluoroacrylate. The latter was found to be a useful intermediate in the synthesis of new heteroyohimbine indole alkaloids possessing a dihydrofuran unit.
unsaturated fluorolactam - fluoroacrylate - cyclisation - heteroyohimbine alkaloids