An Acetylene and a Monoterpene Glycoside from Adenocaulon himalaicum

Abstract

The methanolic extract of the aerial parts of Adenocaulon himalaicum (Asteraceae) has yielded a new acetylene, 1-O-feruloyl-tetradeca-4E,6E,12E-triene-8,10-diyne (1), a new monoterpene glycoside, 9-hydroxylinaloyl-3-O-(4-O-coumaroyl)-β-D-glucopyranoside (2), and eight known compounds. Their structures were established by chemical and spectroscopic methods.

References

• 1 Lee C B. Illustrated Flora of Korea. Seoul, Korea; Hyang Moon Sa 1989: 762
• 2 Ahn D K. Illustrated Book of Korean Medicinal Herbs. Seoul, Korea; Kyo-Hak Publishing Co. Ltd. 1998: 768
• 3 Kulesh N I, Krasovskaya N P, Maksimov O B. Phenolic compounds of Aruncus dioicus and Adenocaulon adhaerescens .  Khim. Prir. Soedin.. 1986;  506 - 7 [C.A., 987; 106: 15743a]
• 4 Sims J J, Pettus J A. Isolation of free cis- and trans-phytol from the red alga Gracilaria andersoniana .  Phytochemistry. 1976;  15 1076-7
• 5 Tschesche R, Hoppe H J, Snatzke G, Wulff G, Fehlhaber H W. Über Parasorbosid, den glykosidischen Vorläufer der Parasorbinsäure aus Vogelbeeren.  Chem. Ber.. 1971;  104 1420-8
• 6 Fujita T, Fumayoshi A, Nakayama M. A phenylpropanoid glucoside from Perilla frutescens .  Phytochemistry. 1994;  37 543-6
• 7 Mizutani K, Yuda M, Tanaka O, Saruwatari Y I, Fuwa T, Jia M R, Ling Y K, Pu X F. Chemical studies on Chinese traditional medicine, Dangshen. I. Isolation of (Z)-3- and (E)-2-hexenyl-β-D-glucosides.  Chem. Pharm. Bull.. 1988;  36 2689-90
• 8 Uchiyama T, Miyase T, Ueno A, Usmanghan K. Terpenic glycosides from Pluchea indica .  Phytochemistry. 1989;  28 3369-72
• 9 Seppanen T, Laakso I, Hiltunen R. Determination of alkoxyglycerols by GC-MS.  Planta Medica. 1988;  54 583
• 10 Pachaly P, Lansing A, Neugebauer M, Sin K S. Acetylene aus Atractylis koreana .  Planta Medica. 1990;  56 469-71
• 11 Aoshima H, Miyase T, Ueno A. Phenylethanoid glycoside from Veronica undulata .  Phytochemistry. 1994;  36 1557-8
• 12 Bohlmann F, Kleine K M. Über die Inhaltsstoffe von Dahlia merckii Lehm.  Chem. Ber.. 1965;  98 872-5
• 13 Kashiwda Y, Nonaka G, Nishioka I, Yamagishi T. Galloyl and hydroxycinnamoyl-glucoses from Rhubarb.  Phytochemistry. 1988;  27 1473-7